Dynamic investigation of hydrocarbon proton exchange membrane Fuel Cell

Document Type : Research Paper

Authors

1 School of Chemical Engineering, Iran University of Science and Technology, Narmak, Tehran 16846-13114, Iran

2 Green Research Center (GRC) & School of Chemical Engineering (SChE); Iran University of Science & Technology, Tehran, Iran

Abstract

Sulfonated polyether ether ketone (SPEEK) is categorized in a nonfluorinated aromatic hydrocarbon proton exchange membrane (PEM) group and considered as a suitable substitute for common per-fluorinated membranes, such as Nafion, due to wider operating temperature, less feed gas crossover, and lower cost. Since modeling results in a better understanding of a phenomenon, in this study a dynamic one-dimensional model of the membrane electrode assembly (MEA) of this membrane is developed. The model includes both gas and electrolyte phases. Species transfer by diffusion and convection in an intra-phase and interphases space and participate in electrochemical reactions. The catalyst layers are modeled in detail with catalyst agglomerates covered with a layer of electrolyte and feed gas transfers into the electrolyte phase by Henry’s low. Then the gas diffuses to the catalyst surface on which it reacts electrochemically. The polarization curve of this MEA obtained from the model is validated against experimental data and shows acceptable agreement. Concentration profiles in the MEA both in the gas and electrolyte phase with time are also presented as results.

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Main Subjects


[1]        Ohira A. and Kuroda S., "Differences in the oxygen permeation behavior of perfluorinated and hydrocarbon-type polymer electrolyte membranes at elevated temperatures," Eur. Polym. J., 2015, 67: 78
[2]        Dai H., Guan R., Li C., and Liu J., "Development and characterization of sulfonated poly(ether sulfone) for proton exchange membrane materials," Solid State Ionics, 2007, 178: 339
[3]        Kim Y. S., Einsla B., Sankir M., Harrison W., and Pivovar B. S., "Structure–property–performance relationships of sulfonated poly(arylene ether sulfone)s as a polymer electrolyte for fuel cell applications," Polymer, 2006, 47: 4026
[4]        Matsumoto K., Higashihara T., and Ueda M., "Locally and Densely Sulfonated Poly(ether sulfone)s as Proton Exchange Membrane," Macromolecules, 2009, 42: 1161
[5]        Bae B. et al., "Sulfonated Poly(arylene ether sulfone ketone) Multiblock Copolymers with Highly Sulfonated Blocks. Long-Term Fuel Cell Operation and Post-Test Analyses," ACS Applied Materials & Interfaces, 2011, 3: 2786
[6]        Bae B., Miyatake K., and Watanabe M., "Sulfonated Poly(arylene ether sulfone ketone) Multiblock Copolymers with Highly Sulfonated Block. Synthesis and Properties," Macromolecules, 2010, 43: 2684
[7]        Parcero E., Herrera R., and Nunes S. P., "Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application," Journal of Membrane Science, 2006, 285: 206
[8]        Karlsson L. E. and Jannasch P., "Polysulfone ionomers for proton-conducting fuel cell membranes: 2. Sulfophenylated polysulfones and polyphenylsulfones," Electrochimica Acta, 2005, 50: 1939
[9]        Aoki M., Asano N., Miyatake K., Uchida H., and Watanabe M., "Durability of sulfonated polyimide membrane evaluated by long-term polymer electrolyte fuel cell operation," J. Electrochem. Soc., 2006, 153: A1154
[10]      Perrot C., Gonon L., Marestin C., and Gebel G., "Hydrolytic degradation of sulfonated polyimide membranes for fuel cells," Journal of Membrane Science, 2011, 379: 207
[11]      Pu H. and Liu Q., "Methanol permeability and proton conductivity of polybenzimidazole and sulfonated polybenzimidazole," Polym. Int., 2004, 53: 1512
[12]      Xu H., Chen K., Guo X., Fang J., and Yin J., "Synthesis of novel sulfonated polybenzimidazole and preparation of cross-linked membranes for fuel cell application," Polymer, 2007, 48: 5556
[13]      Huang R. Y. M., Shao P., Burns C. M., and Feng X., "Sulfonation of poly(ether ether ketone)(PEEK): Kinetic study and characterization," J. Appl. Polym. Sci., 2001, 82: 2651
[14]      Gil M., Ji X., Li X., Na H., Eric Hampsey J., and Lu Y., "Direct synthesis of sulfonated aromatic poly(ether ether ketone) proton exchange membranes for fuel cell applications," Journal of membrane science, 2004, 234: 75
[15]      Xing P., Robertson G. P., Guiver M. D., Mikhailenko S. D., Wang K., and Kaliaguine S., "Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes," Journal of membrane science, 2004, 229: 95
[16]      Muthu Lakshmi R. T. S., Choudhary V., and Varma I. K., "Sulphonated poly(ether ether ketone): Synthesis and characterisation," Journal of Materials Science, 2005, 40: 629
[17]      Parnian M. J., Rowshanzamir S., and Gashoul F., "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel cell applications," Energy, 2017, 125: 614
[18]      He S., Lin Y., Ma H., Jia H., Liu X., and Lin J., "Preparation of sulfonated poly(ether ether ketone) (SPEEK) membrane using ethanol/water mixed solvent," Mater. Lett., 2016, 169: 69
[19]      Carbone A., Pedicini R., Portale G., Longo A., D’Ilario L., and Passalacqua E., "Sulphonated poly(ether ether ketone) membranes for fuel cell application: Thermal and structural characterisation," J. Power Sources, 2006, 163: 18
[20]      Do K. N. T. and Kim D., "Synthesis and characterization of homogeneously sulfonated poly(ether ether ketone) membranes: Effect of casting solvent," J. Appl. Polym. Sci., 2008, 110: 1763
[21]      Li W., Zhang F., Yi S., Huang C., Zhang H., and Pan M., "Effects of casting solvent on microstructrue and ionic conductivity of anhydrous sulfonated poly(ether ether ketone)-inoic liquid composite membranes," Int. J. Hydrogen Energy, 2012, 37: 748
[22]      Jun M.-S., Choi Y.-W., and Kim J.-D., "Solvent casting effects of sulfonated poly(ether ether ketone) for Polymer electrolyte membrane fuel cell," Journal of Membrane Science, 2012, 396: 32
[23]      Li X. et al., "Fabrication of sulfonated poly(ether ether ketone ketone) membranes with high proton conductivity," Journal of Membrane Science, 2006, 281: 1
[24]      Lee J. K., Li W., and Manthiram A., "Sulfonated poly(ether ether ketone) as an ionomer for direct methanol fuel cell electrodes," J. Power Sources, 2008, 180: 56
[25]      Yang B. and Manthiram A., "Sulfonated Poly(ether ether ketone) Membranes for Direct Methanol Fuel Cells," Electrochem. Solid-State Lett., 2003, 6: A229
[26]      Sayadi P., Rowshanzamir S., and Parnian M. J., "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, 2016, 94: 292
[27]      Anderson K. et al., "Infrared spectroscopy of ion-induced cross-linked sulfonated poly(ether ether ketone)," Polymer, 2016, 93: 65
[28]      Zhao Y.-y., Tsuchida E., Choe Y.-K., Ikeshoji T., Barique M. A., and Ohira A., "Ab initio studies on the proton dissociation and infrared spectra of sulfonated poly(ether ether ketone) (SPEEK) membranes," Phys. Chem. Chem. Phys., 2014, 16: 1041
[29]      Mahajan C. V. and Ganesan V., "Atomistic Simulations of Structure of Solvated Sulfonated Poly(ether ether ketone) Membranes and Their Comparisons to Nafion: I. Nanophase Segregation and Hydrophilic Domains," The Journal of Physical Chemistry B, 2010, 114: 8357
[30]      Komarov P. V., Veselov I. N., Chu P. P., Khalatur P. G., and Khokhlov A. R., "Atomistic and mesoscale simulation of polymer electrolyte membranes based on sulfonated poly(ether ether ketone)," Chem. Phys. Lett., 2010, 487: 291
[31]      Weber A. Z. et al., "A Critical Review of Modeling Transport Phenomena in Polymer-Electrolyte Fuel Cells," J. Electrochem. Soc., 2014, 161: F1254
[32]      Poornesh K. K. and Cho C., "Stability of Polymer Electrolyte Membranes In Fuel Cells: Initial Attempts To Bridge Physical And Chemical Degradation Modes," Fuel Cells, 2015, 15: 196
[33]      Qin C. Z. and Hassanizadeh S. M., "A new approach to modelling water flooding in a polymer electrolyte fuel cell," Int. J. Hydrogen Energy, 2015, 40: 3348
[34]      Cao T.-F., Mu Y.-T., Ding J., Lin H., He Y.-L., and Tao W.-Q., "Modeling the temperature distribution and performance of a PEM fuel cell with thermal contact resistance," Int. J. Heat Mass Transfer, 2015, 87: 544
[35]      Chippar P. and Ju H., "Numerical modeling and investigation of gas crossover effects in high temperature proton exchange membrane (PEM) fuel cells," Int. J. Hydrogen Energy, 2012,
[36]      Chippar P. and Ju H., "Three-dimensional non-isothermal modeling of a phosphoric acid-doped polybenzimidazole (PBI) membrane fuel cell," Solid State Ionics, 2012, 225: 30
[37]      Knauth P. and Di Vona M. L., "Hydration and proton conductivity of ionomers: the model case of Sulfonated Aromatic Polymers," Frontiers in Energy Research, 2014, 2:
[38]      Cheddie D. and Munroe N., "Review and comparison of approaches to proton exchange membrane fuel cell modeling," J. Power Sources, 2005, 147: 72
[39]      Qiu X., Dong T., Ueda M., Zhang X., and Wang L., "Sulfonated reduced graphene oxide as a conductive layer in sulfonated poly(ether ether ketone) nanocomposite membranes," Journal of Membrane Science, 2017, 524: 663